A porous 3D heterometal-organic framework containing both lanthanide and high-spin Fe(ii) ions.

نویسندگان

  • Bin Zhao
  • Xiao-Yan Chen
  • Zhi Chen
  • Wei Shi
  • Peng Cheng
  • Shi-Ping Yan
  • Dai-Zheng Liao
چکیده

The first porous 3D [Ln-Fe] heterometal-organic frameworks incorporating high-spin Fe(ii) ions were structurally characterized with fascinating 1D channels and higher thermal stability: the robust frameworks still keep intact on removing free H(2)O or adsorbing C(2)H(5)OH, and the luminescence of [Eu-Fe] complex displays selective detection of Mg(2+).

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عنوان ژورنال:
  • Chemical communications

دوره 21  شماره 

صفحات  -

تاریخ انتشار 2009